So, x-axis is Voltage with min at 2.9V and max at 3.0V, and y-axis is standard deviation of time predictions (interpolated from smoothers) at a given voltage. Right?
If that's the case, you'll probably need to re-create those smoothing splines in Fit Y by X for each block and save the predicted values to the table so you can get those predictions. If you have each block as a separate column, you can add a few more rows to the get the predicted time at each voltage value you want. Then, you could compute the standard deviation of the predicted values for each row to get the sigma values for your plot. If you could post your data table, I could show you what I mean.
-- Cameron Willden