Hi @Cristian,
Welcome to the community!
I only spot checked a few of these, but I don't see any mismatches. The connecting letters report is constructed such that any levels that share a level do not have a statistically significant difference. Since there are only 3 comparisons that are statistically significant in the table, it's easy to verify that those match. For example "HPS,no" vs. "HPS,yes" has a p-value < 0.001. In the connecting letters report, "HPS,no" has letters A D E, and "HPS,yes" has letters "B C". Since none of those letters match, the table and letters are consistent. Same follows for "B6_G5_R89,no" vs "B6_G5_R89,yes" and "Control,no" vs. "Control,yes".
I have to admit this is the most unusual looking connecting letters report I have seen. The reason is the std. error for all of the other comparisons is 5.023. Notice that if the compared levels have the same chemical, the standard error is only 0.932? How is your data structured? Is this a split plot experiment by chance?
*Edit: Good eye Mark on spotting those inconsistencies.
-- Cameron Willden