Your follow-up question has me concerned.
For correlations (or the agreement statistic) you have observations that are matched. I thought that the inside measurement for row number 1 of your dataset was for person #1 (l will use the name "Fred"). "Fred" also provided the value in row number 1 for your outside measurement. One way to think about this is: Could I reorder all of the values in one column and still have the data make sense? If the answer is that reordering one columns would destroy the dataset validity, then the columns are matched. If the answer is that the reordering is fine, then the data are not matched and you have two independent samples.
If your samples ARE matched, then how did you end up with more observations for one column than the other?
If the samples are NOT matched, then the analysis advice that you have been given so far is not correct. You are looking to see if the two independent samples are different from each other. You will need to restructure you data table to perform that analysis, which will be equivalent to a two-sample proportion test which answers the question: is the proportion of 1's for population 1 different from the proportion of 1's for population 2?
Respond if you really have the two independent samples information. If you do, then the details can be given on how to structure your data and get that test.
Dan Obermiller