Hi @Ake ,
If you want to "tag" someone in the forums use the "@" symbol and then the web interface will suggest people to tag -- usually only those related to the thread, but if you know another user's name, you can type that in and it'll bring up their link.
Anyway, if your data comes from a physical process, then I would imagine that there should be a known equation that explains the decay curve that is observed. But, JMP can still do what you want. It actually helps that your data is in a stacked format.
One way you can do this is the following: go Analyze > Specialized Modeling > Fit Curve, then cast the columns as shown.
You'll get a screen that looks like this, go to the red hot-button > Exponential Growth and Decay > Fit Exponential 2P (two-parameter):
You then get this in the report output:
If you go to the red hot-button next to Exponential 2P then select Save Formulas > Save Prediction Formula
You'll then get a column in your data table that has the prediction formula based on the "Type":
You can see the values at :Time=0 are very close to the original values. And if you do a graph builder of V vs V Predictor(), see the green script I saved to the data table. I have some scripts saved to the data table that you can check out. You can try swapping the Sample and Type in the Group and Z. They result in slightly different models, because one is grouped by :Sample and the other by :Type.
This should get you want you want. When grouped by type, you can see the decay constants in the exponents are not identical to each other. The only other way you can fix the values of the y-intercept (that I can think of) is to do a fit y by x with Type in the By field. But, you'll want to do a transformation of the V column by taking the log of it. The graphs should now be linear and when you fit a line to the data, you can then do Fit Special... and force the y-intercept to the correct value of the log of the initial V -- I've saved a script to the data table that you can review -- it is set up to do each sample and type separately. The slopes are not the same, so the exponential decay constants won't be the same either.
All this should at least get you well on your way. Cool data set and project by the way!
Hope this helps!,
DS