I looked at your attached file. There is a 3rd column named SN (tin?). SN is only 1 when HCL is collected. Ra is collected with SN of 1, 2, 3, 4 or 5. There was a little variation in RA for different levels of SN, so I subsetted just the rows where SN==1. The data is not collected at the same time of day. But I saw no variation by time of day.
JMP correlation needs matched data or imputed data. Instead of correlation, look at the time trends of Ra and HCL concentration with an exponentially weighted moving average. Ra looks like it has been trending down, while HCL concentation has different periods. Create a column for the day and summarize Ra and HCL by day. Then use Bivariate as Jim suggested. The results are below. Note the means of the control charts and teh means of the correlation are not identical, since the means on the control charts are using all the data and teh correlation is the mean of the daily means.