Most likely there are other options but here are few (I'm using JMP's Big Class as example table).
One option is to overlay two identical pie charts and then use custom formatting for the "N" label (you could do that for % label, but it easier to do for N), in this case I added row change to the custom format
You could also create new column which has those "label" values and use that for your pie chart.
New Column("Column 6",
Character,
"Nominal",
Formula(
"N: " || Char(Col Number(:sex, :sex)) || "
" ||
Char((100 * Col Number(:sex, :sex)) / Col Number(:sex)) || "%"
),
Set Selected
)
-Jarmo