In general, test of significance (p-values) are tests based on rejecting or not rejecting the Null Hypothesis. The p-value is the associated probability of a Type 1 or alpha error (rejecting the Null when the Null is true). These tests can be done on different statistics with different associated probability distributions (e.g., t, F, Chi square, etc). The Parameter Estimates reports the coefficients of the model and Prob>|t| is the probability a value greater than the calculated t Ratio (Estimate/Std Error) could exist by chance alone (this is actually area of the probability distribution, in this case Student's t-distribution beyond the calculated test statistic) . Effects tests use the calculated F ratio (mean square effect/mean square error) in the same way. The Prob>F is the probability a value greater than the calculated F-Ratio could exist by chance alone (i.e., when the effect = 0).
This picture might clarify graphically what is being calculated.
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"All models are wrong, some are useful" G.E.P. Box