Thanks for sharing the screenshots. I wonder if there's something about the data that makes the estimation result in these small differences, especially given the large differences in variances. If you'd like to share your data (via tech support or DM) I could give you more details. However, what I'd expect to see is the same estimates. The attached script uses a simulated sample data table to fit the same two models and the results are as expected:
As a side note, you might consider adding covariances in these models, unless you truly expect those to be zero. Specifically, in the path model the residual covariance between GABA and FA might be needed, and in the regression model, the covariances between age, GABA, and FA, would be customary to include.
Best,
~Laura
Laura C-S