We cannot use information criteria, such as AICc, to assess significance. They are more of a probabilistic statement. The smaller the AICc, then the larger the likelihood of the parameters, given the fixed data, with a penalty for model complexity. The penalty is the same for all of your candidate models, so the difference is entirely the likelihood.
If they are highly correlated, then they are redundant. (No independent information) Can you pick one from prior theory or knowledge?
Are the predictor levels set or measured?
The logistic curves in the plot show a decrease in the probability of each of the ordinal levels as the predictor levels increase. The slope is negative. The ordinal logistic regression uses cumulative logits. The odds are not about one level versus another but sums of logits versus other sums. You could use the generalized logit in a nominal logistic regression analysis if that form of odds is more meaningful or useful.
You could try adding square of the IV to the model and compare AICc to decide if there is an improvement. The response (logit) might not be linear.