Hi @SelectionIguana ,
Your data has a dependency over the X axis (i.e. the time) which is to be expected with curved data, these shapes can appear in near perfect 'functional' models and are a product of the systematic curvature because the relationship between X and Y is not linear. Even with a perfect fit, residuals can cluster in patterns due to the model’s shape (here's an example of a model below with RSq of 0.99 but different residuals). You'll also likely see greater variation at different parameters, ie the values may always be bigger at the asymptote vs. the location.

I'm sure others will add to this, but unless there's an obvious trend difference that you can grab from the residuals, I would focus on the other model test parameters.
Thanks,
Ben
“All models are wrong, but some are useful”