Hi @aatw,
The ordering of your nominal level for the categorical factor "Solution" is the same as the order you have specified when naming the levels 1, 2, 3 when defining the factors in your DoE. You can check this by creating the design and looking at the column property "Value Order" :

So if you have defined your solution levels in this order : "Distilled water", "Tap water", "NaCl", then these values correspond to Solution 1, Solution 2, Solution 3.
You can move your mouse to each terms intersection to better understand to which terms the correlation value is associated. If you look at the example below for the second row/first column or first row second column (same info), you'll see a correlation coefficient value of 0 for the terms Solution 1 x Solution 2, corresponding to Distilled water x Tap water :

If you change the value order property, it will of course change the correlation matrix, as Solution 1 will no longer be linked to Distilled water, but to the new level you have put in first place.
Hope this will help you,
Victor GUILLER
"It is not unusual for a well-designed experiment to analyze itself" (Box, Hunter and Hunter)